1.須要開電變開關嗎?
--> esc can be 'off' (but not 100% sure)
2.A123 充滿電會超過6.6V ,對接收會有影響嗎?
--> When fully charge, 2SA123 is about 7.4v so it is slightly over voltage. It should be 90% safe to servo & receiver. but you may add a voltage regulator to drop it to 6.0v to be on the safe side.
I think 2S123 @ 6.6v (or 7.4v charged) can plug directly into the receiver without problem. Some people even plug in 2S lipo directly. Also 5cell NiMh full charged will be around 7.2v and people has been using 5cell NiMh as Rx battery for a long time without problem.
Of course with a 6V regulator is the best, just a little bit bigger/heavier.